Rhodium(III)- and Ruthenium(II)-Catalyzed Olefination of Isoquinolones

被引：99

作者：

Zhao, Peng ^{[1
]}

Niu, Rui ^{[1
]}

Wang, Fen ^{[1
]}

Han, Keli ^{[1
]}

Li, Xingwei ^{[1
]}

机构：

[1] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

来源：

ORGANIC LETTERS | 2012年 / 14卷 / 16期

关键词：

C-H BONDS; COPPER-CATALYZED ARYLATION; OXIDATIVE ALKENYLATION; DIRECTED ALKENYLATION; AROMATIC KETIMINES; 3+2 ANNULATION; FUNCTIONALIZATION; ALKYNES; ACTIVATION; HYDROARYLATION;

D O I：

10.1021/ol3018352

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

NH and N-protected isoquinolones undergo Rh(III)-catalyzed oxidative olefination at the 8-position. Complementary redox-neutral olefination of such isoquinolones using internal alkynes was achieved under ruthenium catalysis.

引用

页码：4166 / 4169

页数：4

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