Macrocyclic Bis(phenanthroline-pyrrole): A Convenient One-Pot Synthesis, Structure(s), Spectroscopic, and Redox Properties, and the Binding of Amine Guests, Protons, and Lanthanide Ions

被引：13

作者：

McSkimming, Alex ^{[1
]}

Shrestha, Sumi ^{[1
]}

Bhadbhade, Mohan M. ^{[2
]}

Thordarson, Pall ^{[1
]}

Colbran, Stephen B. ^{[1
]}

机构：

[1] Univ New S Wales, Sch Chem, Sydney, NSW 2052, Australia

[2] Univ New S Wales, Mark Wainwright Analyt Ctr, Sydney, NSW 2052, Australia

来源：

CHEMISTRY-AN ASIAN JOURNAL | 2014年 / 9卷 / 01期

基金：

澳大利亚研究理事会;

关键词：

cooperative effects; europium dimer; lanthanides; macrocycles; photo-dehydrochlorination; EXPANDED PORPHYRINS; CRYSTAL-STRUCTURE; ANION-BINDING; METAL-IONS; CD-II; PB-II; HG-II; COMPLEXES; AROMATICITY; RECOGNITION;

D O I：

10.1002/asia.201301053

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This paper reports a convenient, one-pot, easily scalable and readily modifiable synthesis of a novel large-ring bis(1,10-phenanthrolinyl-2,5-pyrrole) macrocycle, H2LMC, and describes its spectroscopic and electrochemical properties, protonation, cooperative amine binding, electrocatalysis of the oxidation of primary amines, photosensitization of the decomposition of dichloromethane, and the first lanthanide complexes of the hexaaza-dianion L-MC(2-) including the novel dimer, [(NO3)(L-MC)Eu(-OH)Eu(L-MC)(H2O)(2)]2py.

引用

页码：136 / 145

页数：10