Study on the reaction of amines with internal epoxides

被引：16

作者：

Radojcic, Dragana ^{[1
]}

Hong, Jian ^{[1
]}

Ionescu, Mihail ^{[1
]}

Wan, Xianmei ^{[1
]}

Javni, Ivan ^{[1
]}

Petrovic, Zoran S. ^{[1
]}

机构：

[1] Pittsburg State Univ, Kansas Polymer Res Ctr, 1701 South Broadway St, Pittsburg, KS 66762 USA

来源：

EUROPEAN JOURNAL OF LIPID SCIENCE AND TECHNOLOGY | 2016年 / 118卷 / 10期

关键词：

Amine; Internal epoxide; Reaction; ACIDS;

D O I：

10.1002/ejlt.201500490

中图分类号：

TS2 [食品工业];

学科分类号：

0832 ;

摘要：

The reactivity of internal epoxides, as in epoxidized fatty acids, with primary amines was investigated using primary amines and a model epoxide compound, which was a mixture involving cis- and trans-isomers of 9,10-epoxyoctadecane. The reactions were carried out at 100, 170, and 200 degrees C for 24 h. It was observed that the reaction of an amine with an internal epoxide does not proceed to any significant extent even at 200 degrees C in the absence of catalysts.

引用

页码：1507 / 1511

页数：5

共 50 条

[1] MECHANISM OF ACID CATALYZED REACTION OF AMINES WITH EPOXIDES
LABANA, SS
CHANG, YF
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1973, : 48 - &
[2] REACTION OF BROMO EXOXIDES AND ACETOXY EPOXIDES WITH AMINES
HASSNER, A
CATSOULACOS, P
JOURNAL OF ORGANIC CHEMISTRY, 1967, 32 (03): : 549 - +
[3] REACTION OF ASYMMETRIC DIACETYLENIC ALPHA-EPOXIDES WITH AMINES
SHILNIKOVA, LN
PERVEEV, FY
ZHURNAL ORGANICHESKOI KHIMII, 1978, 14 (02): : 251 - 256
[4] Mechanism of the reaction of epoxides with β-hydroxyalkylmercaptans upon catalysis by tertiary amines
Demochkin, V.V.
Malievskii, A.D.
Kinetics and Catalysis, 1988, 29 (2 pt 1) : 312 - 318
[5] REACTION OF ALPHA EPOXIDES WITH CARBOXYLIC-ACIDS AND TERTIARY-AMINES
PIROZHNAYA, LN
GROMOV, VV
ZHURNAL ORGANICHESKOI KHIMII, 1973, 9 (01): : 210 - 210
[6] BIS(TRIFLUOROMETHYL) EPOXIDES .2. REACTION-RATES WITH AMINES
GRIFFITH, JR
OREAR, JG
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1972, : 55 - &
[7] CALORIMETRIC INVESTIGATION OF POLYMERIZATION REACTIONS .3. CURING REACTION OF EPOXIDES WITH AMINES
HORIE, K
HIURA, H
SAWADA, M
MITA, I
KAMBE, H
JOURNAL OF POLYMER SCIENCE PART A-1-POLYMER CHEMISTRY, 1970, 8 (06): : 1357 - &
[8] MECHANISM OF EPOXIDES REACTIONS WITH AMINES
VLADIMIROV, LV
ARTEMENKO, SA
IVANOV, VV
ZELENETSKII, AN
OLEYNIK, YF
SALAMATINA, OB
VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A, 1980, 22 (01): : 225 - 230
[9] MECHANISM OF THE REACTION OF EPOXIDES WITH BETA-HYDROXYALKYLMERCAPTANS UPON CATALYSIS BY TERTIARY-AMINES
DEMOCHKIN, VV
MALIEVSKII, AD
KINETICS AND CATALYSIS, 1988, 29 (02) : 312 - 318
[10] REACTIVITY OF INTERNAL EPOXIDES
WONG, CM
HILL, LW
JOURNAL OF PAINT TECHNOLOGY, 1973, 45 (587): : 63 - 68

← 1 2 3 4 5 →