Highly selective recognition of fluoride anion through direct deprotonation of intramolecularly hydrogen-bonded phenolic hydroxyl groups

被引：29

作者：

Zhang, Xiang ^{[1
]}

Fu, Jie ^{[2
]}

Zhan, Tian-Guang ^{[2
]}

Dai, Liyan ^{[1
]}

Chen, Yingqi ^{[1
]}

Zhao, Xin ^{[2
]}

机构：

[1] Zhejiang Univ, Dept Chem & Biol Engn, Hangzhou 310027, Peoples R China

[2] Chinese Acad Sci, Shanghai Inst Organ Chem, Shanghai 200032, Peoples R China

来源：

TETRAHEDRON LETTERS | 2013年 / 54卷 / 37期

关键词：

Recognition; Fluoride; Phenol; Deprotonation; Hexaazatriphenylene; PROTON-TRANSFER; BINDING AGENTS; DRINKING-WATER; RECEPTORS; IONS; EFFICIENT; UREA; NMR;

D O I：

10.1016/j.tetlet.2013.07.021

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel chemosensor for fluoride anion has been developed. This sensor, constructed by merging six phenolyl units into a hexaazatriphenylene (HAT) core, could recognize F- visually and spectroscopically with high selectivity over other anions, which was demonstrated by naked-eye experiment and UV-vis absorption spectroscopy study. (C) 2013 Elsevier Ltd. All rights reserved.

引用

页码：5039 / 5042

页数：4

共 7 条

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