Photorefractive properties of poly(N-vinyl carbazole)-based composites for high-speed applications

被引:124
|
作者
Díaz-García, MA
Wright, D
Casperson, JD
Smith, B
Glazer, E
Moerner, WE
Sukhomlinova, LI
Twieg, RJ
机构
[1] Univ Calif San Diego, Dept Chem, La Jolla, CA 92093 USA
[2] Kent State Univ, Dept Chem, Kent, OH 44242 USA
关键词
D O I
10.1021/cm981157h
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The photorefractive properties of polymer composites based on poly(N-vinylcarbazole), doped with the sensitizer C-60, the plasticizer butyl benzyl phthalate, and two series of chromophores are presented. The influence of the structure and the oxidation potential of the chromophore on the photorefractive properties is discussed. These materials show promise for video-rate optical processing applications,since they exhibit fast response times (beam-coupling growth times, tau(g), as small as 60 ms at 50 V/mu m applied field and 200 mW/cm(2) intensity and tau(g) as small as 5 ms at 100 V/mu m and 1 W/cm(2)).
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页码:1784 / 1791
页数:8
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