Catalytic Hydrogen Oxidation: Dawn of a New Iron Age

被引：45

作者：

Simmons, Trevor R. ^{[1
]}

Artero, Vincent ^{[1
]}

机构：

[1] Univ Grenoble 1, CEA, CNRS, Lab Chem & Biol Met, F-38054 Grenoble 9, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 24期

基金：

欧洲研究理事会;

关键词：

bioinorganic chemistry; homogeneous catalysis; hydrides; hydrogen; hydrogenases; NIFE HYDROGENASES; ACTIVE-SITE; H-2; COMPLEXES; ELECTROCATALYSTS; RELEVANT; ELECTRON; MODELS;

D O I：

10.1002/anie.201302908

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

One metal or two? Recent results in the design of hydrogenase mimics have resulted in NiFe- and Fe-based complexes (see picture) that split molecular H2 into electrons and protons. Although these compounds are still far from technological application they improve our understanding of how nature exploits abundant metals to achieve complex reactions. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：6143 / 6145

页数：3

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