Atomic vibrational dynamics of amorphous Fe-Mg alloy thin films

The atomic vibrational dynamics of Fe-57 in 800-angstrom thick amorphous FexMg1-x alloy thin films (0.3 <= x <= 0.7) has been investigated at room temperature by nuclear resonant inelastic X-ray scattering (NRIXS) of 14.4125 keV synchrotron radiation. The amorphous phase has been successfully stabilized by codeposition of Fe and Mg in ultrahigh vacuum onto a substrate held at -140 degrees C during deposition. The amorphous structure of the samples was confirmed by X-ray diffraction and conversion electron Mossbauer spectroscopy. The Fe-57-projected partial vibrational density of states, g(E), has been obtained from the measured NRIXS vibrational excitation probability, together with thermodynamic quantities such as the probability of recoilless absorption (f-factor), the average kinetic energy per Fe atom, the average force constant, and the vibrational entropy per Fe atom. A plot of g(E)/E-2 versus E proves the existence of non-Debye-like vibrational excitations with a peak at E-bp similar to 3-5 meV (boson peak). Both the boson peak height and Ebp were found to depend linearly on the composition x. Above the boson peak, g(E)/E-2 exhibits an exponential decrease. (c) 2005 Elsevier Ltd. All rights reserved.