Unified meso-pores and dense Cu2+ sites in porous coordination polymers for highly efficient gas storage and separation

被引：22
|
作者：
Lyu, Hongliang [1 ]
Zhang, Qiang [1 ]
Wang, Yang [1 ]
Duan, Jingui [1 ]
机构：
[1] Nanjing Tech Univ, State Key Lab Mat Oriented Chem Engn, Coll Chem Engn, Nanjing 210009, Jiangsu, Peoples R China
来源：
DALTON TRANSACTIONS | 2018年 / 47卷 / 13期
基金：
中国国家自然科学基金;
关键词：
METAL-ORGANIC FRAMEWORK; HYDROGEN STORAGE; CO2; BENCHMARK; BINDING; DESIGN;
D O I：
10.1039/c8dt00512e
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Unified meso-pores and dense open metal sites (OMS) in porous coordination polymers (PCPs) allow highly promising H-2 and C2-hydrocarbon storage, as well as rapid and efficient C2H2/4 enrichment from CO2 mixtures. The positive function of the OMS, associated with guest thermodynamics, was well revealed by in situ infrared (IR) spectroscopy study.
引用
收藏
页码：4424 / 4427
页数：4
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