Pyridine Adducts of Nickel(II) Xanthates as Single-Source Precursors for the Aerosol-Assisted Chemical Vapor Deposition of Nickel Sulfide

被引:85
|
作者
Alam, Navee [2 ]
Hill, Michael S. [1 ]
Kociok-Koehn, Gabriele [1 ]
Zeller, Matthias [3 ]
Mazhar, Muhammad [2 ]
Molloy, Kieran C. [1 ]
机构
[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England
[2] Quaid I Azam Univ, Dept Chem, Islamabad 45320, Pakistan
[3] Youngstown State Univ, Dept Chem, Youngstown, OH 44555 USA
关键词
D O I
10.1021/cm801330v
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Compounds of the type [Ni((S2COBu)-Bu-n)(2)center dot(py)(2)] (py = pyridine derivative) have been synthesized and Studied as single-source precursors for the fabrication of phase-pure thin films of rhombohedral (Millerite) NiS by aerosol-assisted chemical vapor deposition. The films have been characterized by XRD, SEM. EDX, and AFM and have been found to display a substrate-dependent morphology that is effectively independent of the precise identity of the precursor complex, regardless of minor variations in thermal stability.
引用
收藏
页码:6157 / 6162
页数:6
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