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- [1] Uncharted TerritoryAMERICAN FAMILY PHYSICIAN, 2010, 81 (04) : 421 - 421Maurer, Mary AnnCrawford-Faucher, Amy
- [4] Uncharted territory? Orr, A. (alanorr2003@yahoo.co.uk), 1600, Institution of Engineering and Technology (13):
Reaction engineering with enzymes: A relatively uncharted territory
被引：6
|作者：
Puskas, Judit E.
[1
]
Kantor, Jozsef
[1
]
Shrikhande, Gayatri
[1
]
机构：
[1] Univ Akron, Dept Chem & Biomol Engn, Akron, OH 44325 USA
关键词：
transesterification;
vinyl methacrylate;
2-hydroxyethyl acrylate;
Candida antarctica lipase B;
new kinetic model;
LIPASE-CATALYZED TRANSESTERIFICATION;
ISOBUTYLENE;
POLYMERIZATION;
KINETICS;
ACETATE;
D O I：
10.1002/aic.15544
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
This article discusses the history of enzyme kinetics developed by Michaelis and Menten, and recent work extending kinetics for enzyme-catalyzed reactions in organic solvents. Based on kinetic studies of the transesterification of vinyl methacrylate with 2-hydroxyethyl acrylate catalyzed by Candida antarctica lipase B, a new model is proposed that resembles the kinetic model of controlled/living polymerizations governed by dynamic equilibrium of active and dormant species. Experimental data indicates that by judicious selection of reaction conditions steady-state conditions can be achieved and very clean products with quantitative conversion can be produced. (c) 2016 American Institute of Chemical Engineers AIChE J, 63: 266-272, 2017
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页码：266 / 272
页数：7
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