SYNTHESIS AND CHARACTERIZATION OF AMMONIUM-, PYRIDINIUM-, AND PYRROLIDINIUM-BASED SULFONAMIDO FUNCTIONALIZED IONIC LIQUIDS

被引：3
|
作者：
Saravanamurugan, Shunmugavel [1 ]
Fehrmann, Rasmus [1 ]
Riisager, Anders [1 ]
机构：
[1] Tech Univ Denmark, Ctr Catalysis & Sustainable Chem, Dept Chem, DK-2800 Lyngby, Denmark
来源：
SYNTHETIC COMMUNICATIONS | 2012年 / 42卷 / 22期
关键词：
Amine; ionic liquid; methanesulfonyl; sulfonamido; tosyl; SOLUBILITIES; CATALYSIS;
D O I：
10.1080/00397911.2011.582597
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
New homologous ammonium-, pyridinium-, and pyrrolidinium-based sulfonamido functionalized ionic liquids have been synthesized in two steps using monoethanolamine, methanesulfonyl chloride, and tosyl chloride as precursors with ethanol as solvent. Attempts to synthesize dual amino functionalized ionic liquid containing both a primary and a secondary amine group in the same ionic liquid are also reported. All functionalized ionic liquids were characterized by H-1 and C-13 NMR. Melting point and thermal stability of the functionalized ionic liquids were measured by differential scanning calorimetry and thermogravimetric analysis.
引用
收藏
页码：3383 / 3394
页数：12
相关论文
共 50 条
  • [1] Thermochemistry of the pyridinium- and pyrrolidinium-based ionic liquids
    Sergey P. Verevkin
    Ricardas V. Ralys
    Vladimir N. Emel’yanenko
    Dzmitry H. Zaitsau
    Christoph Schick
    Journal of Thermal Analysis and Calorimetry, 2013, 112 : 353 - 358
  • [2] Thermochemistry of the pyridinium- and pyrrolidinium-based ionic liquids
    Verevkin, Sergey P.
    Ralys, Ricardas V.
    Emel'yanenko, Vladimir N.
    Zaitsau, Dzmitry H.
    Schick, Christoph
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2013, 112 (01) : 353 - 358
  • [3] Aging Effects on the Properties of Imidazolium-, Quaternary Ammonium-, Pyridinium-, and Pyrrolidinium-Based Ionic Liquids Used in Fuel and Energy Production
    Fox, Elise B.
    Smith, L. Taylor
    Williamson, Tyler K.
    Kendrick, Sarah E.
    ENERGY & FUELS, 2013, 27 (11) : 6355 - 6361
  • [4] A perturbed hard-sphere equation of state for phosphonium-, pyridinium-, and pyrrolidinium-based ionic liquids
    Sayed Mostafa Hosseini
    Ionics, 2010, 16 : 571 - 575
  • [5] A perturbed hard-sphere equation of state for phosphonium-, pyridinium-, and pyrrolidinium-based ionic liquids
    Hosseini, Sayed Mostafa
    IONICS, 2010, 16 (06) : 571 - 575
  • [6] PVT properties of imidazolium-, phosphonium-, pyridinium- and pyrrolidinium-based ionic liquids using critical point constants
    Mozaffari, Farkhondeh
    Mousavi, Seyed Mohammad Reza
    PHYSICS AND CHEMISTRY OF LIQUIDS, 2017, 55 (01) : 11 - 18
  • [7] Exploring enthalpies of formation of imidazolium-, pyridinium-, and pyrrolidinium-based ionic liquids with dicyanamide anion using quantum chemical methods
    Asakereh, Zahra
    Zare, Morteza
    Shakerzadeh, Ehsan
    JOURNAL OF MOLECULAR LIQUIDS, 2020, 308
  • [8] Synthesis and applications of chiral pyrrolidinium-based ionic liquids
    Kronenwetter, Hannah
    Etz, Brian
    Manchanayakage, Renuka
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 247
  • [9] Exploring enthalpies of formation of imidazolium-, pyridinium-, and pyrrolidinium-based ionic liquids with dicyanamide anion using quantum chemical methods
    Asakereh, Zahra
    Zare, Morteza
    Shakerzadeh, Ehsan
    Zare, Morteza (m.zare@scu.ac.ir), 1600, Elsevier B.V., Netherlands (308):
  • [10] Contrasting Thermosolvatochromic Trends in Pyridinium-, Pyrrolidinium-, and Phosphonium-Based Ionic Liquids
    Khupse, Nageshwar D.
    Kumar, Anil
    JOURNAL OF PHYSICAL CHEMISTRY B, 2010, 114 (01): : 376 - 381
12345