Growth of zeolitic imidazolate framework-8 crystals from the solid-liquid interface

被引:29
|
作者
Zhu, Minqi [1 ]
Jasinski, Jacek B. [2 ]
Carreon, Moises A. [1 ]
机构
[1] Univ Louisville, Dept Chem Engn, Louisville, KY 40292 USA
[2] Univ Louisville, Conn Ctr Renewable Energy Res, Louisville, KY 40292 USA
基金
美国国家科学基金会;
关键词
METAL-ORGANIC FRAMEWORK; ROOM-TEMPERATURE SYNTHESIS; MOLECULAR-SIEVE MEMBRANE; CAPTURE PROPERTIES; SECONDARY GROWTH; SEPARATION; ZIF-8; FILMS; FUNCTIONALIZATION; SELECTIVITY;
D O I
10.1039/c2jm30718a
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We demonstrate the synthesis of ZIF-8 crystals from the solid-liquid interface. Specifically, ZIF-8 was grown from zinc foil in the presence of concentrated 2-methylimidazole alcohol solutions. The solution pH and reducing environment were identified as key parameters in the formation of a pure ZIF-8 phase.
引用
收藏
页码:7684 / 7686
页数:3
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