Synthesis and optical resolution of novel chiral silanols

被引：0
|
作者：
Mori, A [1 ]
Toriyama, F
Kajiro, H
Hirabayashi, K
Nishihara, Y
Hiyama, T
机构：
[1] Tokyo Inst Technol, Resources Utilizat Res Lab, Yokohama, Kanagawa 2268503, Japan
[2] Kyoto Univ, Grad Sch Engn, Dept Chem Mat, Sakyo Ku, Kyoto 6068501, Japan
来源：
CHEMISTRY LETTERS | 1999年 / 07期
关键词：
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Silanols bearing an asymmetric center on silicon, methyl(2-phenylethenyl) (3,3,3-trifluoropropyl)silanol and methyl(phenyl)(vinyl)silanol are synthesized by alkylative cleavages of cyclic siloxanes with an organolithium. Optical resolution of their enantiomers is performed by HPLC with a chiral stationary phase column. Optical characters of thus separated enantiomers are also examined.
引用
收藏
页码：549 / 550
页数：2
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