Syntheses, Crystal Structures, and Spectra Properties of Two New M(II) [M = Cu and Ni] Macrocyclic Complexes

被引：0
|
作者：
Ren, Shi [1 ]
Ma, Shu-Lin [1 ]
机构：
[1] Tianjin Univ Commerce, Coll Sci, Dept Applicat Chem, Tianjin 300134, Peoples R China
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2012年 / 42卷 / 08期
关键词：
H-bond; macrocyclic complex; tetraaza macrocyclic; 3D network structure; MAGNETIC-PROPERTIES; COPPER(II) COMPLEXES; ZINC(II) COMPLEXES; NICKEL(II); ASSEMBLIES; COMPOUND; WATER; MODE;
D O I：
10.1080/15533174.2012.680143
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new macrocyclic complexes, [ML](ClO4)(2)center dot 4,4'-bpy [M = Cu (1) and Ni (2), L = 1,3,6,9,11,14-hexaazatricyclo [12.2.1.1(6,9)]octadecane, 4,4'-bpy = 4,4'-bipyridine], have been synthesized and structurally characterized by X-ray crystallography analyses. Complex 1 crystallizes in the triclinic crystalline system of space group P-1, while complex 2 crystallizes in the monoclinic crystalline system of space group P2(1)/n. In the both complexes, M(II) [M = Cu (1) and Ni (2)] centers are located in a distorted square plane environment. The weakly interactions raised the structure unit to a 3D network.
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收藏
页码：1105 / 1109
页数：5
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