Field-Directed Self-Assembly with Locking Nanoparticles

被引:37
|
作者
Motornov, Mikhail [2 ]
Malynych, Sergiy Z. [1 ]
Pippalla, Deepthi S. [2 ]
Zdyrko, Bogdan [1 ]
Royter, Halyna [2 ]
Roiter, Yuri [2 ]
Kahabka, Mathew [2 ]
Tokarev, Alexander [1 ]
Tokarev, Ihor [2 ]
Zhulina, Ekaterina [3 ]
Kornev, Konstantin G. [1 ]
Luzinov, Igor [1 ]
Minko, Sergiy [2 ]
机构
[1] Clemson Univ, Sch Mat Sci & Engn, Clemson, SC 29634 USA
[2] Clarkson Univ, Dept Chem & Biomol Sci, Potsdam, NY 13699 USA
[3] Russian Acad Sci, Inst Macromol Cpds, St Petersburg 199004, Russia
基金
美国国家科学基金会;
关键词
Nanoparticles; nanostructures; self-assembly; FABRICATION; MOLECULE; COLLOIDS;
D O I
10.1021/nl301780x
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A reversible locking mechanism is established for the generation of anisotropic nanostructures by a magnetic field pulse in liquid matrices by balancing the thermal energy, short-range attractive and long-range repulsive forces, and dipole dipole interactions using a specially tailored polymer shell of nanoparticles. The locking mechanism is used to precisely regulate the dimensions of self-assembled magnetic nanoparticle chains and to generate and disintegrate three-dimensional (3D) nanostructured materials in solvents and polymers.
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页码:3814 / 3820
页数:7
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