Infrared spectroscopic and ab initio study of HOOClO2

被引：8

作者：

Svensson, T ^{[1
]}

Nelander, B ^{[1
]}

Bernhardsson, A ^{[1
]}

Karlström, G ^{[1
]}

机构：

[1] Chem Ctr Lund, S-22100 Lund, Sweden

来源：

JOURNAL OF PHYSICAL CHEMISTRY A | 1999年 / 103卷 / 23期

关键词：

D O I：

10.1021/jp990070w

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

HOOClO2 was produced by addition of hydrogen atoms to a mixture of O-2 and OClO on the surface of growing argon matrixes at 17 K. The compound was identified by infrared spectroscopy utilizing the H to D and O-18(2) and O-16,18(2) spectral shifts. The matrices were irradiated with the full radiation from a 300-W Xe lamp. HOOClO2 was eliminated by the irradiation, but we were unable to identify the photodecomposition product. Ab initio calculations show that HOO binds to OClO with a bond strength intermediate between a van der Waals interaction and a covalent bond.

引用

页码：4432 / 4437

页数：6

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