Microwave assisted greener synthesis of nickel nanoparticles using sodium hypophosphite

被引：50
|
作者：
Eluri, Ravi [1 ]
Paul, Brian [1 ]
机构：
[1] Oregon State Univ, Corvallis, OR 97330 USA
来源：
MATERIALS LETTERS | 2012年 / 76卷
关键词：
Nickel nanoparticles; Microwave; Sodium hypophosphite; Propylene glycol; TEM; POLYOL PROCESS; SIZE;
D O I：
10.1016/j.matlet.2012.02.049
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Nickel nanoparticle (NiNP) was synthesized by reduction of less toxic nickel acetate tetrahydrate (Ni(CH3CO2)(2)center dot 4H(2)O) precursor, using sodium hypophosphite monohydrate (NaPH2O2 center dot H2O) under microwave irradiation. By varying the molar ratio of [Ni+2]/[NaPH2O2]/[NaOH], NiNP of 3.8 to 7.1 nm was obtained. Increasing NaOH concentration resulted in morphological change from isolated spherical particles (7.2 +/- 1.5 nm) to agglomerated nano flowers (72 +/- 14 nm). Phase analysis and interplanar spacing measurements confirmed the particles as fcc-Ni. Quantitative analysis showed the presence of P and O due to HPO2(-) radical in reaction product. Addition of small amounts of polyvinylpyrolidone (PVP) or cetyltrimethylammonium bromide (CTAB) resulted in slight increase in particle size. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码：36 / 39
页数：4
相关论文
共 50 条
  • [1] Microwave-assisted synthesis of nickel nanoparticles
    Xu, Wei
    Liew, Kong Yong
    Liu, Hanfan
    Huang, Tao
    Sun, Chuntao
    Zhao, Yanxi
    MATERIALS LETTERS, 2008, 62 (17-18) : 2571 - 2573
  • [2] Microwave -Assisted Synthesis and Characterization of Nickel Ferrite Nanoparticles
    Carpenter, Gopal
    Sen, Ravindra
    Malviya, Nitin
    Gupta, Nitish
    ADVANCED MATERIALS AND RADIATION PHYSICS (AMRP-2015), 2015, 1675
  • [3] Synthesis of highly stable dispersions of copper nanoparticles using sodium hypophosphite
    Lai, Dongzhi
    Liu, Tao
    Jiang, Guohua
    Chen, Wenxing
    JOURNAL OF APPLIED POLYMER SCIENCE, 2013, 128 (03) : 1443 - 1449
  • [4] Rapid synthesis of copper nanoparticles by sodium hypophosphite reduction in ethylene glycol under microwave irradiation
    Zhu, HT
    Zhang, CY
    Yin, YS
    JOURNAL OF CRYSTAL GROWTH, 2004, 270 (3-4) : 722 - 728
  • [5] Microwave-assisted synthesis of silver nanoparticles using sodium alginate and their antibacterial activity
    Zhao, Xihui
    Xia, Yanzhi
    Li, Qun
    Ma, Xiaomei
    Quan, Fengyu
    Geng, Cunzhen
    Han, Zhenyu
    COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2014, 444 : 180 - 188
  • [6] Microwave-assisted synthesis of disulfides using tetrathiomolybdate: A step toward greener synthesis
    Sidiq, Naheed
    Bhat, Mohsin Ahmad
    Khan, Khaliquz Zaman
    Khuroo, Mohammad Akbar
    HETEROATOM CHEMISTRY, 2012, 23 (04) : 373 - 376
  • [7] Glycine assisted synthesis of nickel ferrite nanoparticles by auto-combustion method using microwave radiation
    Tadjarodi, Azadeh
    Chamani, Sanaz
    20TH INTERNATIONAL ELECTRONIC CONFERENCE ON SYNTHETIC ORGANIC CHEMISTRY (ECSOC), 2016,
  • [8] Microwave-Assisted Synthesis of Monodisperse Nickel Nanoparticles Using a Complex of Nickel Formate with Long-Chain Amine Ligands
    Yamauchi, Tomohisa
    Tsukahara, Yasunori
    Sakamoto, Tetsuo
    Kono, Takumi
    Yasuda, Makoto
    Baba, Akio
    Wada, Yuji
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2009, 82 (08) : 1044 - 1051
  • [9] Greener synthesis of subphthalocyanines using microwave heating
    Nissenbaum, David
    McConnell, Chris
    Jurow, Matthew
    Drain, Charles
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2012, 244
  • [10] Microwave-assisted greener synthesis of Silver nanoparticles using Entada rheedii leaf extract and investigation of its anticancer and antimicrobial properties
    Mathew, Anjaly
    Ravindran, Ramesh Analiparambil
    Vazhanthodi, Abdul Rasheed
    Sivadasan, Binitha Valiyaparambil
    Ovungal, Sabira
    Subrahmanian, Sujith Madathilpadi
    Chittadimangalath, Prasant
    Parambil, Ajaykumar Anthyalam
    INTERNATIONAL JOURNAL OF NANO DIMENSION, 2022, 13 (03) : 329 - 334
12345