C-C bond-forming desulfurizations of sulfoximines

被引：11
|
作者：
Reggelin, M. [1 ]
Slavik, S. [1 ]
Buehle, P. [1 ]
机构：
[1] Tech Univ Darmstadt, Clemesn Schopf Inst Organ Chem & Biochem, D-64287 Darmstadt, Germany
来源：
ORGANIC LETTERS | 2008年 / 10卷 / 18期
关键词：
D O I：
10.1021/ol8015995
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Highly substituted, enantiomerically pure azaheterocyclic ring systems play an important role in medicinal chemistry as potential peptide mimetics. Metalated 2-alkenyl sulfoximines offer an efficient entry to this class of compounds. In this paper, we describe a new means to remove the sulfonimidoyl auxiliary with concomitant formation of a C-C double bond.
引用
收藏
页码：4081 / 4084
页数：4
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