Novel, regioselective transformation of an oxirane system. An efficient approach to the synthesis of endocannabinoid 2-arachidonoylglycerol

被引：19
|
作者：
Stamatov, SD
Stawinski, J
机构：
[1] Paisij Hilendarski Univ Plovdiv, Dept Chem Technol, BG-4000 Plovdiv, Bulgaria
[2] Univ Stockholm, Arrhenius Lab, Dept Organ Chem, S-10691 Stockholm, Sweden
[3] Polish Acad Sci, Inst Bioorgan Chem, PL-61704 Poznan, Poland
来源：
TETRAHEDRON LETTERS | 2002年 / 43卷 / 09期
关键词：
2-acylglycerol; 2-arachidonoylglycerol; glycidyl arachidonate; acyl migration;
D O I：
10.1016/S0040-4039(02)00116-8
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A trifluoroacetic anhydride-catalysed opening of the oxirane system of glycidyl arachidonate with a simultaneous migration of the acyl group provides a new, efficient entry to 2-arachidonoylglycerol. (C) 2002 Published by Elsevier Science Ltd.
引用
收藏
页码：1759 / 1761
页数：3
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