More on the phase diagram of laponite

被引:117
|
作者
Ruzicka, B
Zulian, L
Ruocco, G
机构
[1] Univ Roma La Sapienza, Dipartimento Fis, I-00185 Rome, Italy
[2] Univ Roma La Sapienza, INFM, CRS, SOFT, I-00185 Rome, Italy
[3] Univ Perugia, Dipartimento Fis, I-06123 Perugia, Italy
关键词
D O I
10.1021/la0524418
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The phase diagram of a charged colloidal system (Laponite) has been investigated by dynamic light scattering in a previously unexplored range of salt and clay concentrations. Specifically, the clay weight and salt molar concentrations have been varied in the ranges C-w = 0.004 divided by 0.025 and C-s = (1 X 10(-3), 5 x 10(-3)) M, respectively. As in the case of free salt water samples (C, 1 x 10(-4) M), an aging dynamics toward two different arrested phases is found in the whole examined Cw and C, range. Moreover a transition between these two different regimes is found. It is clear from these measurements that a revision of the phase diagram is necessary and a new "transition" line between two different arrested states is drawn.
引用
收藏
页码:1106 / 1111
页数:6
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