Direct template synthesis of a heterometallic CoIII/ZnII complex: The advantage of using a metal powder as a starting material

被引：9
|
作者：
Shevchenko, Denys V. [1 ]
Kokozay, Vladimir N. [1 ]
Krasovska, Marina V. [2 ]
Shishkin, Oleg V. [2 ]
机构：
[1] Natl Taras Shevchenko Univ Kyiv, Dept Inorgan Chem, UA-01033 Kiev, Ukraine
[2] Natl Acad Sci Ukraine, STC Inst Single Crystals, UA-61001 Kharkov, Ukraine
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2008年 / 11卷 / 10期
关键词：
Direct synthesis; Template synthesis; Cobalt; Zinc; Crystal structure;
D O I：
10.1016/j.inoche.2008.07.013
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The heterometallic complex [Co(L-1)Cl-2][ZnCl3(DMF)] (L-1 = 4,6,6-trimethyl-1,9-diamino-3,7-diazanon-3-ene) has been obtained by direct template synthesis from cobalt powder, zinc oxide, zinc chloride, ethylenediamine dihydrochloride and acetone in dimethylformamide and characterized by X-ray crystallographic analysis. The mechanism of the complex formation is suggested. (C) 2008 Elsevier B.V. All rights reserved.
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收藏
页码：1209 / 1211
页数：3
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