Design of chiral tin(IV) aryloxide as a mild Lewis acid catalyst for enantioselective Diels-Alder reaction

被引：7
|
作者：
Kano, T [1 ]
Konishi, T [1 ]
Konishi, S [1 ]
Maruoka, K [1 ]
机构：
[1] Kyoto Univ, Grad Sch Sci, Dept Chem, Sakyo Ku, Kyoto 6068502, Japan
来源：
TETRAHEDRON LETTERS | 2006年 / 47卷 / 06期
关键词：
asymmetric catalysis; Lewis acids; Sn; Diels-Alder reaction;
D O I：
10.1016/j.tetlet.2005.12.001
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A novel Sn(IV) aryloxide Lewis acid has been designed and prepared from SnCl4 and (S)-3,3'-bis(3,5-bis(trifluoromethyl)phenyl)-1,1'-bi-2-naphthol. The chiral Sn(IV) Lewis acid has been successfully applied to the enantioselective Diels-Alder reaction. (c) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码：873 / 875
页数：3
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