Iron Sulfide Catalyzed Redox/Condensation Cascade Reaction between 2-Amino/Hydroxy Nitrobenzenes and Activated Methyl Groups: A Straightforward Atom Economical Approach to 2-Hetaryl-benzimidazoles and -benzoxazoles

被引：137

作者：

Thanh Binh Nguyen ^{[1
]}

Ermolenko, Ludmila ^{[1
]}

Al-Mourabit, Ali ^{[1
]}

机构：

[1] CNRS, Inst Chim Subst Nat, Ctr Rech Gif Sur Yvette, F-91198 Gif Sur Yvette, France

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2013年 / 135卷 / 01期

关键词：

ELEMENTAL SULFUR; SELECTIVE REDUCTION; HIGHLY EFFICIENT; BENZOTHIAZOLES; SOLVENT; DERIVATIVES; ACCESS; BENZIMIDAZOLES; MILD; ACID;

D O I：

10.1021/ja311780a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Iron sulfide generated in situ from elemental sulfur and iron was found to be highly efficient in catalyzing a redox/condensation cascade reaction between 2-amino/hydroxy nitrobenzenes and activated methyl groups. This method represents a straightforward and highly atom economical approach to 2-hetaryl-benzimidazoles and -benzoxazoles.

引用

页码：118 / 121

页数：4

共 2 条

[1] Iron sulfide catalyzed redox/condensation cascade reaction between 2-amino/hydroxy nitrobenzenes and activated methyl groups: A straightforward atom economical approach to 2-hetaryl-benzimidazoles and -benzoxazoles
Nguyen, T.B. (nguyen@icsn.cnrs-gif.fr), 1600, American Chemical Society (135):
[2] Tandem Electrochemical Redox/Condensation Reaction Between 2-Amino Nitrobenzenes and Aliphatic Alcohols: An Approach to Benzimidazoles
Zhang, Zenghui
Yang, Wenjing
Liu, Changji
Yu, Xiao
Song, Shuyong
Xia, Chengcai
ADVANCED SYNTHESIS & CATALYSIS, 2024, 366 (22) : 4667 - 4673

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