Preparation and properties of uniform colloidal particles of mixed copper(II)-lanthanide(III) compounds

被引:2
|
作者
Porta, F
Alessi, M
Paolo, C
Bianchi, CL
机构
[1] CTR CNR, I-20133 MILAN, ITALY
[2] UNIV MILAN, DIPARTIMENTO CHIM STRUTTURALE & STEREOCHIM INORGA, I-20133 MILAN, ITALY
[3] UNIV MILAN, DIPARTIMENTO CHIM FIS & ELETTROCHIM, I-20133 MILAN, ITALY
[4] UNIV FLORENCE, DIPARTIMENTO CHIM, I-50134 FLORENCE, ITALY
关键词
colloids; copper; lanthanide; magnetism;
D O I
10.1016/0927-7757(95)03430-7
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Colloidal spherical particles with narrow size distribution, of mixed compounds of copper and rare earth ions, were obtained by ageing solutions containing Cu(NO3)(2) + L(NO3)(3), (L = Gd, Dy, Ho, Er) in the presence of urea. The amorphous products consisting of mixed basic hydrous carbonates of Cu and L were converted by calcination to the corresponding ternary oxides with well-defined composition. Composition and magnetic properties of these oxides are discussed.
引用
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页码:305 / 313
页数:9
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