Assemblies at the Liquid-Solid Interface: Chirality Expression from Molecular Conformers

被引：5

作者：

Shen, Yong-Tao ^{[1
,5
]}

Zhu, Ning-Bo ^{[3
,4
]}

Zhang, Xue-Mei ^{[1
]}

Lei, Shengbin ^{[6
,7
]}

Wei, Zhongqing ^{[2
]}

Li, Min ^{[2
]}

Zhao, Dahui ^{[3
,4
]}

Zeng, Qing-Dao ^{[1
]}

Wang, Chen ^{[1
]}

机构：

[1] Natl Ctr Nanosci & Technol NCNST, Beijing 100190, Peoples R China

[2] Chinese Acad Sci, Inst High Energy Phys, CAS Key Lab Biomed Effects Nanomat & Nanosafety, Beijing 100049, Peoples R China

[3] Peking Univ, Dept Appl Chem, BNLMS, Beijing 100871, Peoples R China

[4] Peking Univ, Key Lab Polymer Chem & Phys, Minist Educ, Coll Chem, Beijing 100871, Peoples R China

[5] Tianjin Univ, Dept Sch Mat Sci & Engn, Tianjin Key Lab Composite & Funct Mat, Tianjin 300072, Peoples R China

[6] Harbin Inst Technol, Key Lab Microsyst & Microstruct Mfg, Minist Educ, Harbin 150080, Peoples R China

[7] Harbin Inst Technol, Acad Fundamental & Interdisciplinary Sci, Harbin 150080, Peoples R China

来源：

CHEMPHYSCHEM | 2013年 / 14卷 / 01期

基金：

中国国家自然科学基金;

关键词：

chirality; conformational analysis; foldamers; self-assembly; surface analysis; METAL-SURFACES; KAGOME; CRYSTALLIZATION; NETWORKS;

D O I：

10.1002/cphc.201200730

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Two foldamer molecular conformers and their self-assemblies are investigated by STM at liquid/solid interfaces. A chiral structure can be obtained both from the adsorption of the two different conformers and from the assemblies formed at the liquid-solid interface. This finding suggests a convenient approach to controlling and fabricating 2D chiral nanostructures. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：92 / 95

页数：4

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