Ni(salphen)-based metal-organic framework for the synthesis of cyclic carbonates by cycloaddition of CO2 to epoxides

被引：98

作者：

Ren, Yanwei ^{[1
]}

Shi, Yanchao ^{[1
]}

Chen, Junxian ^{[1
]}

Yang, Shaorong ^{[1
]}

Qi, Chaorong ^{[1
]}

Jiang, Huanfeng ^{[1
]}

机构：

[1] S China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510640, Guangdong, Peoples R China

来源：

RSC ADVANCES | 2013年 / 3卷 / 07期

基金：

中国国家自然科学基金;

关键词：

PROPYLENE CARBONATE; CATALYTIC-ACTIVITY; CRYSTAL-STRUCTURES; HYBRID CATALYST; ION-EXCHANGE; SCHIFF-BASE; COORDINATION; DIOXIDE; MICROPARTICLES; INTERCONVERSION;

D O I：

10.1039/c2ra22550f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A well-defined homogeneous molecular catalyst Ni(salphen) was introduced as a "metalloligand" in a MOF, providing an efficient and recyclable heterogeneous catalyst for the synthesis of cyclic carbonates by the cycloaddition of CO2 to epoxides under relatively mild conditions.

引用

页码：2167 / 2170

页数：4

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