The promoted oxidation of CO induced by the visible-light response of Au nanoparticles over Au/TiO2

被引:28
|
作者
Liu, Junfeng [1 ]
Si, Ruiru [1 ]
Zheng, Huarong [1 ]
Geng, Qiang [1 ]
Dai, Wenxin [1 ]
Chen, Xun [1 ]
Fu, Xianzhi [1 ]
机构
[1] Fuzhou Univ, Res Inst Photocatalysis, Fujian Prov Key Lab Photocatalysis, State Key Lab Breeding Base, Fuzhou 350002, Peoples R China
基金
中国国家自然科学基金;
关键词
Carbon monoxide oxidation; Visible-light response; Localized surface plasmon resonance; Au nanoparticles; GOLD NANOPARTICLES; UV-IRRADIATION; CATALYTIC-OXIDATION; SIZE; ACTIVATION; CLUSTERS; OXYGEN; H-2;
D O I
10.1016/j.catcom.2012.05.011
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A visible light (490-780 nm) was introduced into the process of oxidizing CO over a TiO2 supported Au nanoparticle catalyst (Au/TiO2). It is found that the visible-light irradiation can promote the oxidation of CO over Au/TiO2. Based on the results of both the optical absorption of Au/TiO2 and the adsorption of CO over Au/TiO2, it is proposed that the localized surface plasmon resonance (LSPR) of Au nanoparticles induced by the visible-light would promote the adsorption of CO and its activation at the surface of Au species, resulting in the promoted oxidation of CO over Au/TiO2. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码:136 / 139
页数:4
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