Crystal and molecular structure and luminescence properties of europium trifluoroacetate complex with triphenylphosphine oxide

被引：3
|
作者：
Bukvetskii, B. V. [1 ]
Kalinovskaya, I. V. [1 ]
机构：
[1] Russian Acad Sci, Inst Chem, Far Eastern Branch, Vladivostok 690022, Russia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2013年 / 83卷 / 02期
关键词：
Root Mean Square; Trifluoroacetate; TPPO; Triphenylphosphine Oxide; Europium Compound;
D O I：
10.1134/S1070363213020096
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Using XRD method, we determined the atomic structure of crystals of the compound [Eu(TFA)(3)center dot 2TPPO (H2O)](2), where TFA is a trifluoroacetate anion, TPPO is a triphenylphosphine oxide. The coordination polyhedra of two independent europium atoms with coordination number CN = 8 are isotypic and consist of a antiprism of [EuO8] composition. The geometric and electronic structural features of the compound corresponding to the characteristics of its luminescent properties are discussed. DOI: 10.1134/S1070363213020096
引用
收藏
页码：284 / 288
页数：5
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