Generation and reaction of alkyl radicals in open reaction vessels

被引：10

作者：

Tatunashvili, Elene ^{[1
]}

McErlean, Christopher S. P. ^{[1
]}

机构：

[1] Univ Sydney, Sch Chem, Sydney, NSW 2006, Australia

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2020年 / 18卷 / 39期

关键词：

UNACTIVATED ALKYL; RATE CONSTANTS; ARYL RADICALS; FUNCTIONALIZATION; ACTIVATION; IODIDES; HALIDES;

D O I：

10.1039/d0ob01892a

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An operationally simple process to transform alkyl iodides into reactive alkyl radicals is described. Aryl diazonium salts react with Hantzsch esters and molecular oxygen to give aryl radicals, which participate in halogen atom transfers to give alkyl radicals. These intermediates react with a variety of acceptors. The reaction cascade occurs at room temperature, in open reaction vessels, with short reaction times.

引用

页码：7818 / 7821

页数：4

共 50 条

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