Chemistry of multi-sulfur substituted arenes and sulfur rich heterocycles - Relations to advanced materials

被引：0
|
作者：
Fanghanel, E [1 ]
Alsleben, I [1 ]
Gebler, B [1 ]
Herrmann, A [1 ]
Herrmann, R [1 ]
Palmer, T [1 ]
Strunk, K [1 ]
Ullrich, A [1 ]
Luders, K [1 ]
Mahdjour, H [1 ]
机构：
[1] HOCHSCH TECH WISSENSCH & KUNSTE,FACHBEREICH INFORMAT MATH & NAT WISSENSCH,D-04277 LEIPZIG,GERMANY
来源：
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1997年 / 120卷
关键词：
benzenehexathiol; benzo-1,2,3-trithioles; oligomeric dibenzo-TTF; 2-(fluorene-9-ylidene)-benzo-1,3-dithioles; 2,3,6,7-tetrachloro-naphthalene-1,4,5,8-tetrathiol; oligomeric transition metal complexes; organic ferromagnets; 4H,8H-thiopyrano[3,2-c] thiopyran-4,8-dione-3,7-dicarboxylic acid; cycloaddition reactions;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis and properties of perthio-substituted benzene derivatives and of electron donor molecules with extended pi-conjugation - derived from benzenehexathiol - are described. The corresponding cation radical salts of the donor molecules are characterized as semiconducting solids. From 2,3,6,7-tetrachloro-naphthalene-1,4,5,8-tetrathiol oligomeric nickel and cobalt complexes with ferromagnetic spin ordering between 10 and 20 K are synthesized. The 4H,8H-thiopyrano[3,2-c]thiopyran-4,8-dione-3,7-dicarboxylic acid is obtained by cycloaddition reactions of 3H,6H-[1,2]-dithiolo[3,4-c]dithiole-3,6-dithione with dimethyl acetylenedicarboxylat. This new ligand for oxophilic metal ions gives polymeric complexes with transition metal ions. The crystal structure of the manganese complex was determined.
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页码：121 / 143
页数：23
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