Selective Hydrolysis of O-isopropylidene Derivatives of Sugars and Polyhydroxy Alcohols Catalyzed by Sulfonated Carbon Nanocage

被引:0
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作者
Liu, Min
Li, Ben Hao
Liu, Juan
Li, Xia Bing
Cui, Yi
Li, Fan Shi
Li, Bao Lin [1 ]
机构
[1] Shaanxi Normal Univ, Key Lab, Minist Educ Med Resources & Nat Pharmaceut Chem, Xian 710062, Peoples R China
来源
关键词
O-Isopropylidene Derivatives; Carbohydrates; Selective Hydrolysis; Sulfonated Carbon Nanocage; CHEMOSELECTIVE DEPROTECTION; EFFICIENT; ACETONIDES; ACID; MONOSACCHARIDES; ZEOLITE; ACETALS; SILICA;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A simple, clean and efficient catalyst system for the selective hydrolysis of di-/tri-O-isopropylidene derivatives of sugars and polyhydroxy alcohols to mono-O-isopropylidene derivatives has been developed using sulfonated carbon nanocage (S-CKT) as a reusable catalyst. Compared with reported method, the key advantages of this protocol are shorter reaction time and higher selectivity, simple workup and the recoverability of catalyst.
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页码:749 / 754
页数:6
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