Contribution to modeling the viscosity Arrhenius-type equation for saturated pure fluids

被引:8
|
作者
Tian, Jianxiang [1 ,2 ]
Zhang, Laibin [1 ]
机构
[1] Qufu Normal Univ, Dept Phys, Qufu 273165, Peoples R China
[2] Dalian Univ Technol, Dept Phys, Dalian 116024, Peoples R China
来源
基金
中国国家自然科学基金;
关键词
Temperature; viscosity; Arrhenius equation; SURFACE-TENSION; SELF-DIFFUSION; LIQUID;
D O I
10.1142/S0217979216502027
中图分类号
O59 [应用物理学];
学科分类号
摘要
Recently, Haj-Kacem et al. proposed an equation modeling the relationship between the two parameters of viscosity Arrhenius-type equations [Fluid Phase Equilibria 383, 11 (2014)]. The authors found that the two parameters are dependent upon each other in an exponential function form. In this paper, we reconsidered their ideas and calculated the two parameter values for 49 saturated pure fluids by using the experimental data in the NIST WebBook. Our conclusion is different with the ones of Haj-Kacem et al. We found that (the linearity shown by) the Arrhenius equation stands strongly only in low temperature range and that the two parameters of the Arrhenius equation are independent upon each other in the whole temperature range from the triple point to the critical point.
引用
收藏
页数:13
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