Accurate Control of Multishelled Co3O4 Hollow Microspheres as High-Performance Anode Materials in Lithium-Ion Batteries

被引：692
|
作者：
Wang, Jiangyan [1 ,5 ]
Yang, Nailiang [1 ]
Tang, Hongjie [1 ,5 ]
Dong, Zhenghong [1 ,5 ]
Jin, Quan [1 ]
Yang, Mei [1 ]
Kisailus, David [3 ]
Zhao, Huijun [4 ]
Tang, Zhiyong [2 ]
Wang, Dan [1 ]
机构：
[1] Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China
[2] Natl Ctr Nanosci & Technol, Beijing 100190, Peoples R China
[3] Univ Calif Riverside, Riverside, CA 92521 USA
[4] Griffith Univ, Ctr Clean Environm & Energy, Nathan, Qld 4222, Australia
[5] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 25期
基金：
中国国家自然科学基金;
关键词：
cobalt oxide; electrochemistry; lithium-ion batteries; multishelled hollow microspheres; STORAGE PROPERTIES; HIGH-CAPACITY; ELECTRODES; SPHERES; OXIDE; SYSTEMS; COBALT;
D O I：
10.1002/anie.201301622
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
More than just an empty shell: Multishelled Co3O4 microspheres were synthesized as anode materials for lithium-ion batteries in high yield and purity. As their porous hollow multishell structure guarantees a shorter Li+ diffusion length and sufficient void space to buffer the volume expansion, their rate capacity, cycling performance, and specific capacity were excellent (1615.8 mA h g-1 in the 30th cycle for triple-shelled Co3O4; see graph). Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：6417 / 6420
页数：4
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