A facilely prepared polypyrrole-reduced graphene oxide composite with a crumpled surface for high performance supercapacitor electrodes

被引:90
|
作者
Qian, Tao [1 ]
Yu, Chenfei [1 ]
Wu, Shishan [1 ]
Shen, Jian [1 ,2 ]
机构
[1] Nanjing Univ, Sch Chem & Chem Engn, Nanjing 210093, Jiangsu, Peoples R China
[2] Nanjing Normal Univ, Coll Chem & Mat Sci, Nanjing 210097, Jiangsu, Peoples R China
关键词
D O I
10.1039/c3ta11146f
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A polypyrrole-reduced graphite oxide core-shell composite was facilely fabricated through electrostatic interactions and pi-pi accumulation. This novel composite shows remarkable performance as an electrode material for supercapacitors, with a high specific capacitance of 557 Fg(-1) at a current density of 0.5 Ag-1, and retains a high value after 1000 charge-discharge processes. The maximum energy density of the fabricated supercapacitor based on the mass of active electrodes is calculated to be 49.5 W h kg(-1) and 33.3 W h kg(-1) at a power density of 0.22 kW kg(-1) and 6.06 kW kg(-1), the improved capacitance might be mainly ascribed to higher conductivity and more crumpled surface of the composite.
引用
收藏
页码:6539 / 6542
页数:4
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