It is common knowledge that diffusion theory cannot describe light propagation in semitransparent media, i.e., media with a low optical thickness. However, even in an optically thin slab, late-time transport will be eventually determined by a multiple scattering process whose characteristics are still largely unexplored. We numerically demonstrate that, even for an optical thickness as low as 1, after a short transient, propagation along the slab plane becomes diffusive. Nonetheless, we show that such a diffusion process is governed by modified statistical distributions which result from a highly nontrivial interplay with boundary conditions.