A simple and recyclable copper/DTPA catalyst system for amination of aryl halides with aqueous ammonia in water

被引：18
|
作者：
Yang, Bo [1 ]
Liao, Lihao [1 ]
Zeng, Yongheng [1 ]
Zhu, Xinhai [1 ]
Wan, Yiqian [1 ]
机构：
[1] Sun Yat Sen Univ, Sch Chem & Chem Engn, Guangzhou 510275, Guangdong, Peoples R China
来源：
CATALYSIS COMMUNICATIONS | 2014年 / 45卷
基金：
中国国家自然科学基金;
关键词：
Copper; Amination; Water; Homogeneous catalysis; Recyclable; PRIMARY ARYLAMINES; ANILINES; ARYLATION; CHLORIDES; BROMIDES; IODIDES;
D O I：
10.1016/j.catcom.2013.10.030
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Commercially available CuO/DTPA (diethylenetriaminepentaacetic acid) was established to be a low-cost, recyclable, and environmentally benign homogeneous catalyst system for direct amination of aryl halides with ammonia. Primary aryl amines can be readily prepared from both electron-withdrawing and electron-donating aryl halides in good yields in water without the addition of surfactants. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码：100 / 103
页数：4
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