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Local states of iron ions in multiferroics Bi1-x La x FeO3
被引:26
|作者:
Pokatilov, V. S.
[1
]
Pokatilov, V. V.
[1
]
Sigov, A. S.
[1
]
机构:
[1] Tech Univ, Moscow State Inst Radioengn Elect & Automat, Moscow 119454, Russia
关键词:
MAGNETIC-STRUCTURES;
FE-57;
NMR;
BIFEO3;
FIELDS;
D O I:
10.1134/S1063783409030202
中图分类号:
O469 [凝聚态物理学];
学科分类号:
070205 ;
摘要:
Mossbauer studies of perovskites Bi1-x La (x) FeO3 (x = 0, 0.10, 0.20, 0.61, 0.90, 1.00) were conducted at 295 and 87 K. The spatial spin-modulated structure (SSMS) observed in perovskites BiFeO3 and Bi0.9La0.1FeO3 leads to a specific distribution of hyperfine fields P(B) with two peaks. Substitution of La for Bi (x = 0.2) destructs the SSMS. The concentration dependences of the hyperfine field (B), isomer shift (E >) and quadrupole shift (delta) were measured. The iron ions are in the trivalent state. The local magnetic moments mu(Fe) of the Fe3+ ions are determined.
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页码:552 / 559
页数:8
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