Bis(thioether)silanes: Synthesis and characterization of tin(IV) complexes with new dithioether ligands

被引：1

作者：

Lozano-Lewis, Lissette I. ^{[1
]}

John-Rajkumar, Samuel V. ^{[1
]}

Islas, Susana A. ^{[1
]}

Pike, Robert D. ^{[2
]}

Rabinovich, Daniel ^{[1
]}

机构：

[1] Univ N Carolina, Dept Chem, Charlotte, NC 28223 USA

[2] Coll William & Mary, Dept Chem, Williamsburg, VA 23187 USA

来源：

MAIN GROUP CHEMISTRY | 2007年 / 6卷 / 3-4期

关键词：

bis(thioether) silane complexes; silicon; sulfur; tin; sulfur-donor ligands;

D O I：

10.1080/10241220801962327

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The bis(thioether)silanes Me2Si(CH2SR)(2) (abbreviated Bts(R), where R = Me or Pr-i), the first two members of a new family of bidentate thioether ligands, have been readily prepared and fully characterized. The tin(IV) tetrahalide derivatives (BtsR)SnX4 (X-Cl, Br), which comprise the first four metal coordination complexes of these new sulfur-donor ligands, have also been isolated, and the X-ray structure of the tetrabromide derivative (Bts(Me))SnBr4 confirms the chelating nature of the dithioether.

引用

页码：133 / 142

页数：10

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