Self-Assembly of a Chiral Carbonate- and Cytidine-Containing Dodecanuclear Copper(II) Complex: a Multiarm-Supplied Globular Capsule

被引:29
|
作者
Armentano, Donatella [1 ]
Marino, Nadia [1 ]
Mastropietro, Teresa F. [1 ]
Martinez-Lillo, Jose [1 ]
Cano, Joan [2 ,3 ]
Julve, Miguel [4 ]
Lloret, Francesc [4 ]
De Munno, Giovanni [1 ]
机构
[1] Univ Calabria, Dipartimento Chim, I-87036 Cosenza, Italy
[2] Univ Barcelona, Dept Quim Inorgan, IQTC, E-08028 Barcelona, Spain
[3] Univ Barcelona, ICREA, E-08028 Barcelona, Spain
[4] Univ Valencia, Dept Quim Inorgan, Inst Ciencia Mol, Valencia 46980, Spain
关键词
D O I
10.1021/ic801815s
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A dodecanuclear copper(II) globular-shaped structure has been obtained with the cytidine nucleoside and the templating carbonate anion. It shows receptor properties through anion-cation and multiple anion-pi interactions toward ClO4- as well as an overall antiferromagnetic coupling.
引用
收藏
页码:10229 / 10231
页数:3
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