Phase stability and magnetic properties of a new cobalt(II) coordination polymer based on 2-carboxyethylphosphonate and 1,10′-phenanthroline

被引：3

作者：

Fernandez-Zapico, E. ^{[1
]}

Montejo-Bernardo, J. ^{[1
]}

D'Vries, R. ^{[2
]}

Garcia, J. R. ^{[1
]}

Garcia-Granda, S. ^{[1
]}

Rodriguez Fernandez, J. ^{[3
]}

de Pedro, I. ^{[3
]}

Blanco, J. A. ^{[4
]}

机构：

[1] Univ Oviedo CINN, Dept Quim Fis & Analit & Quim Organ & Inorgan, Oviedo 33006, Spain

[2] CSIC, Inst Ciencias Mat Madrid, E-28049 Madrid, Spain

[3] Univ Cantabria, Fac Ciencias, CITIMAC, E-39005 Santander, Spain

[4] Univ Oviedo, Dept Fis, E-33007 Oviedo, Spain

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 2012年 / 536卷

关键词：

Cobalt; Phosphonates; Phenanthroline; Coordination polymers; Thermal behavior; Magnetic properties; FRAMEWORK; ACID;

D O I：

10.1016/j.jallcom.2012.01.012

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Co-2(HO3PCH2CH2COO)(2)(C12H8N2)(2) has been synthesized from [Co-2(HO3PCH2CH2COO)(2)(C12H8N2)(2)(mu-OH2)](H2O) by thermal treatment (350 degrees C) under inert atmosphere (N-2). The transformation between the initial compound to a red-pink crystalline solid is mediated by an intermediate blue amorphous material. Co-2(HO3PCH2CH2COO)(2)(C12H8N2)(2) is stable in air until 440 degrees C, showing some trends of being magnetically ordered below 2 K. (c) 2012 Elsevier B.V. All rights reserved.

引用

页码：S507 / S510

页数：4

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