Synthesis of Amorphous FeOOH/Reduced Graphene Oxide Composite by Infrared Irradiation and Its Superior Lithium Storage Performance

被引:49
|
作者
Sun, Yongming [1 ]
Hu, Xianluo [1 ]
Luo, Wei [1 ]
Xu, Henghui [1 ]
Hu, Chenchen [1 ]
Huang, Yunhui [1 ]
机构
[1] Huazhong Univ Sci & Technol, State Key Lab Mat Proc & Die & Mould Technol, Sch Mat Sci & Engn, Wuhan 430074, Peoples R China
关键词
FeOOH; MRGO; infrared irradiation; lithium storage performance; HIGH-CAPACITY ANODES; ELECTRODE MATERIALS; ELECTROCHEMICAL PERFORMANCE; ION BATTERIES; LI STORAGE; NANOPARTICLES; ALPHA-FE2O3; GE;
D O I
10.1021/am4028313
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
A new hybrid nanostructure composed of mildly reduced graphene oxide (mRGO) nanosheets and homogeneous loading of amorphous FeOOH with ultrafine particles (similar to 2 nm) is successfully synthesized via a facile infrared irradiation approach. Surprisingly, the as-prepared FeOOH/mRGO hybrid exhibits high reversible capacity, long-term stability, and excellent rate performance, when used as an anode material for lithium-ion batteries. A high reversible capacity of 767 mA h g(-1), with a coulombic efficiency of similar to 100%, can be achieved at a high current density of 1000 mA g(-1) even after 600 discharge/charge cycles. The superior electrochemical performances are attributed to the synergistic effects of the small particle size, amorphous structure, and conductive mRGO.
引用
收藏
页码:10145 / 10150
页数:6
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