Kinetics of the Reduction of Cadmium Sulfate by Thiourea Dioxide in an Aqueous Ammonia Solution upon the Metallization of Carbon Fiber

被引：4

作者：

Polenov, Yu. V. ^{[1
]}

Egorova, E. V. ^{[1
]}

Shestakov, G. A. ^{[1
]}

机构：

[1] Ivanovo State Univ Chem & Technol, Ivanovo 153000, Russia

来源：

RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A | 2018年 / 92卷 / 01期

关键词：

thiourea dioxide; cadmium; carbon fiber; kinetic model; chemical metallization; ACID-BASE PROPERTIES; NICKEL; DECOMPOSITION;

D O I：

10.1134/S0036024418010181

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The kinetics of the decomposition of thiourea dioxide and the reduction of cadmium cations by thiourea dioxide in an aqueous ammonia solution are studied. The kinetic parameters of these reactions are calculated using experimental data, allowing us to adjust conditions for the synthesis of cadmium coatings on carbon fiber of grade UKN-M-12K. The presence of the metal crystalline phase on the fiber is confirmed by means of X-ray diffraction, and its amount is measured via atomic absorption spectroscopy.

引用

页码：53 / 56

页数：4

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