Low-temperature radiation-induced cracking of liquid hydrocarbons

被引：12
|
作者：
Zaikin, Yuriy A. [1 ]
机构：
[1] PetroBeam Inc, Edgewood, NY 11717 USA
来源：
RADIATION PHYSICS AND CHEMISTRY | 2008年 / 77卷 / 09期
关键词：
Liquid hydrocarbons; Low-temperature radiation-induced cracking; Long-living radiation-excited molecular states;
D O I：
10.1016/j.radphyschem.2008.07.001
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Conditions of chain cracking reactions in liquid hydrocarbons at lowered temperatures are discussed subject to contribution of the long-living radiation-excited molecular states. It is predicted that chain reactions of hydrocarbon degradation can proceed without thermal activation at the high dose rates of ionizing irradiation. In this process, both initiation and propagation of the chain are caused only by the action of radiation. Experimental verification has allowed observation of low-temperature chain cracking reactions in high-viscous oil. (C) 2008 Elsevier Ltd. All rights reserved.
引用
收藏
页码：1069 / 1073
页数：5
相关论文
共 50 条
  • [1] LOW-TEMPERATURE RADIATION-INDUCED POLYMERIZATION OF CRYSTALLINE TETRAFLUOROETHYLENE
    BRUK, MA
    ABKIN, AD
    AULOV, VA
    EROSHINA, LV
    CHUIKO, KK
    VYSOKOMOLEKULYARNYE SOEDINENIYA SECTION A, 1972, 14 (04): : 794 - &
  • [2] LOW-TEMPERATURE RADIATION-INDUCED POLYMERIZATION OF CARBON SUBOXIDE
    KIRYUKHIN, DP
    BARKALOV, IM
    GOLDANSKII, VI
    VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A, 1976, 18 (04): : 759 - 762
  • [3] RADIATION-INDUCED POLYMERIZATION OF PURE STYRENE AT LOW-TEMPERATURE
    MACHI, S
    SILVERMA.J
    METZ, DJ
    JOURNAL OF PHYSICAL CHEMISTRY, 1972, 76 (06): : 930 - &
  • [4] LOW-TEMPERATURE DOPING OF SILICON BY RADIATION-INDUCED DIFFUSION
    KOIFMAN, AI
    NARKULOV, AN
    OKSENGENDLER, BL
    YUNUSOV, MS
    PHYSICA STATUS SOLIDI A-APPLIED RESEARCH, 1976, 38 (02): : 439 - 446
  • [5] RADIATION-INDUCED TRANSFORMATIONS OF THE HYDROCARBON MOLECULES IN LOW-TEMPERATURE MATRICES
    FELDMAN, VI
    SUKHOV, FF
    SLOVOKHOTOVA, NA
    BAZOV, VP
    VESTNIK MOSKOVSKOGO UNIVERSITETA SERIYA 2 KHIMIYA, 1995, 36 (04): : 352 - 359
  • [6] Low-temperature annealing of radiation-induced defects in carbon nanotube bundles
    Danilchenko, B. A.
    Voitsihovska, E. A.
    Rogutski, I. S.
    Rudenko, R. M.
    Uvarova, I. Y.
    Yaskovets, I. I.
    DIAMOND AND RELATED MATERIALS, 2017, 80 : 113 - 117
  • [7] LOW-TEMPERATURE RADIATION-INDUCED POLYMERIZATION OF TETRAFLUOROETHYLENE IN A GLASSY PERFLUOROALKANES MATRIX
    ALLAYAROV, SR
    KIRYUKHIN, DP
    ASAMOV, MK
    BARKALOV, IM
    VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A, 1982, 24 (03): : 466 - 471
  • [8] RADIATION-INDUCED RADICALS IN THYMINE AND ITS DERIVATIVES IN LOW-TEMPERATURE GLASSES
    KAALHUS, O
    JOHANSEN, SA
    ANNALS OF THE NEW YORK ACADEMY OF SCIENCES, 1973, 222 (DEC31) : 432 - 445
  • [9] Radiation-induced defects and low-temperature hardening in the Fe–Cr alloy
    A. P. Druzhkov
    V. L. Arbuzov
    D. A. Perminov
    The Physics of Metals and Metallography, 2011, 111 : 212 - 219
  • [10] EFFECT OF PRESSURE ON RADIATION-INDUCED CONDUCTANCE OF LIQUID HYDROCARBONS
    BRAZIER, DW
    FREEMAN, GR
    CANADIAN JOURNAL OF CHEMISTRY, 1969, 47 (06): : 885 - &
12345