The size of the metal ion controls the structures of the coordination polymers of benzo-2,1,3-selenadiazole

被引：16

作者：

Lee, Lucia Myongwon ^{[1
]}

Elder, Philip J. W. ^{[1
]}

Dube, Paul A. ^{[2
]}

Greedan, John E. ^{[1
]}

Jenkins, Hilary A. ^{[1
]}

Britten, James F. ^{[1
]}

Vargas-Baca, Ignacio ^{[1
]}

机构：

[1] McMaster Univ, Dept Chem & Chem Biol, Hamilton, ON L8S 4M1, Canada

[2] McMaster Univ, Brockhouse Inst Mat Res, Hamilton, ON L8S 4M1, Canada

来源：

CRYSTENGCOMM | 2013年 / 15卷 / 37期

关键词：

SELENIUM-NITROGEN HETEROCYCLES; SUPRAMOLECULAR ASSOCIATION; 1,2,5-CHALCOGENADIAZOLES;

D O I：

10.1039/c3ce40752g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The products of the combination of benzo-2,1,3-selenenadiazole with chloride salts of divalent Mn, Fe, Co, Ni, and Cd crystallize from DMSO in two distinct structural types. While the smaller ions form infinite chains of metal atoms N,N'-bridged by the heterocycle, the larger ions stabilize infinite chains of metal atoms bridged by mu(2) halide ions. In the latter case, two heterocycle molecules cap each metal ion and are able to establish a link to the next chain in the lattice through the [Se-N](2) supramolecular synthon. Despite the large (>9.2 angstrom) distance between the [M(mu-Cl)(2)](infinity) chains, the manganese derivative is only paramagnetic.

引用

页码：7434 / 7437

页数：4

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