Synthesis of mesoporous molecular sieves: Influence of aluminum source on Al incorporation in MCM-41

被引：158
|
作者：
Reddy, KM [1 ]
Song, CS [1 ]
机构：
[1] PENN STATE UNIV,DEPT MAT SCI & ENGN,FUEL SCI PROGRAM,UNIVERSITY PK,PA 16802
来源：
CATALYSIS LETTERS | 1996年 / 36卷 / 1-2期
关键词：
mesoporous materials; MCM-41; synthesis; aluminum source;
D O I：
10.1007/BF00807213
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Three series of mesoporous aluminosilicate molecular sieves, MCM-4l, with various Si/A1 ratios were synthesized using different aluminum sources (aluminum isopropoxide, pseudo boehmite and aluminum sulfate). XRD analysis, temperature programmed desorption of n-butylamine, Al-27 and Si-29 MAS NMR, and catalytic alkylation test indicated that aluminum isopropoxide is a better source for incorporating aluminum in the framework of MCM-41 type molecular sieves with better crystallinity and acid characteristics.
引用
收藏
页码：103 / 109
页数：7
相关论文
共 50 条
  • [1] Aluminum incorporation in MCM-41 mesoporous molecular sieves
    Busio, M
    Janchen, J
    vanHooff, JHC
    [J]. MICROPOROUS MATERIALS, 1995, 5 (04): : 211 - 218
  • [2] Aluminum incorporation and interfacial structures in MCM-41 mesoporous molecular sieves
    Janicke, MT
    Landry, CC
    Christiansen, SC
    Kumar, D
    Stucky, GD
    Chmelka, BF
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (28) : 6940 - 6951
  • [3] Synthesis and Characterization of Al MCM-41 Mesoporous Molecular Sieves
    Liu Bai-Jun
    Meng Qing-Lei
    Wang Hui
    Meng Qing-Min
    [J]. ACTA PHYSICO-CHIMICA SINICA, 2010, 26 (12) : 3257 - 3262
  • [4] Synthesis of MCM-41 mesoporous molecular sieves
    Franke, O
    Rathousky, J
    SchulzEkloff, G
    Zukal, A
    [J]. PREPARATION OF CATALYSTS VI: SCIENTIFIC BASES FOR THE PREPARATION OF HETEROGENEOUS CATALYSTS, 1995, 91 : 309 - 318
  • [5] Ti incorporation in MCM-41 mesoporous molecular sieves using hydrothermal synthesis
    Wang, Shengping
    Ma, Changqing
    Shi, Yun
    Ma, Xinbin
    [J]. FRONTIERS OF CHEMICAL SCIENCE AND ENGINEERING, 2014, 8 (01) : 95 - 103
  • [6] Ti incorporation in MCM-41 mesoporous molecular sieves using hydrothermal synthesis
    Shengping WANG
    Changqing MA
    Yun SHI
    Xinbin MA
    [J]. Frontiers of Chemical Science and Engineering, 2014, 8 (01) - 103
  • [7] Ti incorporation in MCM-41 mesoporous molecular sieves using hydrothermal synthesis
    Shengping Wang
    Changqing Ma
    Yun Shi
    Xinbin Ma
    [J]. Frontiers of Chemical Science and Engineering, 2014, 8 : 95 - 103
  • [8] Rapid synthesis for mesoporous molecular sieves MCM-41
    Liu, L
    Xu, H
    Dong, JX
    [J]. TENSIDE SURFACTANTS DETERGENTS, 2006, 43 (01) : 36 - 39
  • [9] The synthesis and characteristics of vanadoaluminosilicate MCM-41 mesoporous molecular sieves
    Lee, DS
    Liu, TK
    [J]. JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 2002, 23 (01) : 15 - 25
  • [10] THE SYNTHESIS AND CHARACTERIZATION OF MESOPOROUS MOLECULAR-SIEVES MCM-41
    SUN, Y
    LIN, WY
    PANG, WQ
    HUO, QS
    [J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 1995, 16 (09): : 1334 - 1338
12345