Cycloaddition Reactions of Carbonyl Ylides Derived From Enones

被引:2
|
作者
Yu, Yang [1 ,2 ]
Cornelissen, Loic [1 ,2 ,3 ]
Wong, Wing-Tak [1 ,2 ]
Chiu, Pauline [1 ,2 ]
机构
[1] Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong, Peoples R China
[2] Univ Hong Kong, State Lab Synthet Chem, Hong Kong, Hong Kong, Peoples R China
[3] Catholic Univ Louvain, Dept Organ & Med Chem, Louvain La Neuve, Belgium
关键词
carbenoids; ylides; cycloaddition; diazo compounds; domino reaction; BETA-KETO-ESTERS; 1,3-DIPOLAR CYCLOADDITIONS; ACID-A; CYCLIZATION; CASCADE; TANDEM; CARBENOIDS; CYCLOISOMERIZATIONS; KOMAROVIQUINONE; CONSTRUCTION;
D O I
10.1055/s-0034-1379926
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The formation of unsaturated carbonyl ylides via rhodium-catalyzed carbene cyclization with enones and their subsequent inter- and intramolecular cycloadditions to construct functionalized oxapolycyclic rings have been realized.
引用
收藏
页码:1553 / 1556
页数:4
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