Nucleation and development of regular microrelief under deformation of polymer with metallic coating

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作者
Volynskii, AL
Voronina, EE
Lebedeva, OV
Bazhenov, SL
Ozerin, AN
Bakeev, NF
机构
[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119899, Russia
[2] Russian Acad Sci, Inst Synthet Polymer Mat, Moscow 117393, Russia
[3] Russian Acad Sci, NN Semenov Chem Phys Inst, Moscow 117977, Russia
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O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Direct microscopic observations showed that, under deformation of rubbery polymers with a thin rigid coating, a regular microrelief develops via the formation of nucleation structures at the surface microinhomogeneities, which are characteristic of real systems. The number of nucleation structures was shown to depend on the stress level of the polymer deformation and on the thickness of the deposited metallic coating. The process of the initiation of the nucleation structures was assumed to be controlled by the Griffith criterion.
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页码:1435 / 1441
页数:7
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