Stereoselectivity in the intramolecular Nozaki-Hiyama-Kishi reaction: influence of the substitution pattern and protecting groups in the construction of 10-membered lactones

被引：11
|
作者：
Pilli, RA [1 ]
Victor, MM [1 ]
机构：
[1] UNICAMP, Inst Quim, BR-13083970 Campinas, SP, Brazil
来源：
TETRAHEDRON LETTERS | 2002年 / 43卷 / 15期
关键词：
D O I：
10.1016/S0040-4039(02)00347-7
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The use of the intramolecular Nozaki-Hiyama-Kishi reaction to construct 10-membered lactones is described. The influence of the nature of the protecting groups at C and C4 and the presence of the methyl group at C9 on the stereochemistry of the newly formed stereogenic center at C7 was investigated. Matched induction led to the preparation of the decanolide moiety with high degree of stereo selection. (C) 2002 Elsevier Science Ltd. All rights reserved.
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页码：2815 / 2818
页数：4
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