Study of Influence of Salt Additives on Mixed Reverse Micelles via Reverse Microemulsion Chromatography and UV-visible Spectroscopy

被引：4
|
作者：
Chaladze, Rusudan [1 ]
Gvaramia, Manuchar [1 ]
Kurtanidze, Manoni [1 ]
Bezarashvili, George [1 ]
Rukhadze, Marina [1 ]
机构：
[1] Ivane Javakhishvili Tbilisi State Univ, Fac Exact & Nat Sci, Dept Chem, GE-0179 Tbilisi, Georgia
来源：
CHEMISTRY LETTERS | 2012年 / 41卷 / 10期
关键词：
BINDING; WATER;
D O I：
10.1246/cl.2012.1035
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Reverse micellar mobile phases based on poly(oxyethylene) (4) lauryl ether (Brij 30) and sodium bis(2-ethylhexyl) sulfosuccinate (AOT) were used as mobile phases in HPLC. The chromatographic behavior of the model compounds was studied on the basis of reverse micellar mobile phases modified by salt additives. The binding of o-nitroaniline (o-NA) to the micelles of Brij 30 was determined by UV-visible spectroscopy. The different influences of kosmotropic and chaotropic anions on the binding constant K-b was revealed. This may be controlled by the different arrangement of kosmotropic and chaotropic ions in the water core of reverse micelles.
引用
收藏
页码：1035 / 1037
页数：3
相关论文
共 8 条
  • [1] Study of influence of ionic additives to AOT reverse microemulsions by liquid chromatography, IR and UV-visible spectroscopy
    Butkhuzi, T.
    Chaladze, R.
    Lominadze, N.
    Rukhadze, M.
    Gvaramia, M.
    Kurtanidze, M.
    Bezarashvili, G.
    Sigua, K.
    COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2014, 442 : 98 - 104
  • [2] On the Formation of New Reverse Micelles: A Comparative Study of Benzene/Surfactants/Ionic Liquids Systems Using UV-Visible Absorption Spectroscopy and Dynamic Light Scattering
    Dario Falcone, R.
    Mariano Correa, N.
    Silber, Juana J.
    LANGMUIR, 2009, 25 (18) : 10426 - 10429
  • [3] PREFERENTIAL SOLVATION OF A DIPOLAR SOLUTE IN MIXED BINARY SOLVENT - A STUDY BY UV-VISIBLE SPECTROSCOPY
    CHATTERJEE, P
    BAGCHI, S
    JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (08): : 3311 - 3314
  • [4] On the possibility that cyclodextrins' chiral cavities can be available on AOT n-heptane reverse micelles.: A UV-visible and induced circular dichroism study
    Silva, O. Fernando
    Silber, Juana J.
    de Rossi, Rita H.
    Correa, N. Mariano
    Fernandez, Mariana A.
    JOURNAL OF PHYSICAL CHEMISTRY B, 2007, 111 (36): : 10703 - 10712
  • [5] Study on the Polarity of bmimPF6/Tween80/toluene Microemulsion Characterized by UV-Visible Spectroscopy
    Zheng, Yongjun
    Eli, Wumanjiang
    JOURNAL OF DISPERSION SCIENCE AND TECHNOLOGY, 2009, 30 (05) : 698 - 703
  • [6] Study of structural changes of water confined in Brij-30 reverse micelles: Revealing influence of ionic additives
    Kurtanidze, Manoni
    Butkhuzi, Tinatin
    Rukhadze, Marina
    Kokiashvili, Nino
    Bezarashvili, George
    Marcus, Julien
    Kunz, Werner
    Sigua, Ketevan
    COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2017, 519 : 98 - 105
  • [7] Characterization of water/sodium bis(2-ethylhexyl) sulfosuccinate/sodium bis(amyl) sulfosuccinate/n-heptane mixed reverse micelles and w/o microemulsion systems: The influence of water and sodium bis(amyl) sulfosuccinate content
    Kljajic, Alen
    Bester-Rogac, Marija
    Trost, Sabina
    Zupet, Rok
    Pejovnik, Stane
    COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2011, 385 (1-3) : 249 - 255
  • [8] Structural Characterization of a Mixed Langmuir-Blodgett Film of a Merocyanine Dye Derivative-Deuterated Arachidic Acid Binary System and the Influence of Successive Hydrothermal Treatment in the Liquid Phase on the Film as Investigated by Polarized UV-Visible and IR Absorption Spectroscopy
    Hirano, Yoshiaki
    Yamazaki, Asuka
    Maio, Ari
    Kitahama, Yasutaka
    Ozaki, Yukihiro
    JOURNAL OF PHYSICAL CHEMISTRY B, 2010, 114 (33): : 10782 - 10792
1