Formation of CH2=TiF2 by C-F activation and α-F transfer

被引：13
|
作者：
Lyon, JT [1 ]
Andrews, L [1 ]
机构：
[1] Univ Virginia, Dept Chem, Charlottesville, VA 22904 USA
来源：
ORGANOMETALLICS | 2006年 / 25卷 / 06期
关键词：
D O I：
10.1021/om060019w
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Laser-ablated titanium atoms react with CH2F2 to form the methylidene complex CH2=TiF2, which is symmetrical and shows no agostic distortion, in contrast to the analogous methylidene complexes CH2=TiHF and CH2=TiH2.
引用
收藏
页码：1341 / 1343
页数：3
相关论文
共 50 条
  • [1] CALCULATION OF C=C AND C-F BOND LENGTHS IN CH2=CH2, CH2=CHF, CIS-CHF=CHF, AND CH2=CF2
    BAK, B
    KIERKEGA.C
    PAPPAS, J
    SKAARUP, S
    ACTA CHEMICA SCANDINAVICA, 1973, 27 (01): : 363 - 364
  • [2] INFRARED AND RAMAN-SPECTROSCOPIC STUDIES ON MOLECULAR-CONFORMATIONS OF F(CH2)3F, F(CH2)4F, F(CH2)5F, F(CH2)5F, F(CH2)6F
    MATSUURA, H
    SAKAKIBARA, M
    MURATA, H
    CHEMISTRY LETTERS, 1982, (07) : 951 - 952
  • [3] Activation and Formation of Aromatic C-F Bonds
    LaBerge, Nicole A.
    Love, Jennifer A.
    ORGANOMETALLIC FLUORINE CHEMISTRY, 2015, 52 : 55 - 111
  • [4] Synthesis and Reactivity of the Fluoro Complex trans-[Pd(F)(4-C5NF4)(iPr2PCH2CH2OCH3)2]: C-F Bond Formation and Catalytic C-F Bond Activation Reactions
    Breyer, David
    Braun, Thomas
    Klaering, Paul
    ORGANOMETALLICS, 2012, 31 (04) : 1417 - 1424
  • [5] ω-Monofluoroalkylrhodoximes:: synthesis and structures of [Rh{(CH2)nF)(dmgH)2(PPh3)] (n=1, 3) and C-F activation reactions
    Rausch, M
    Bruhn, C
    Steinborn, D
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 622 (1-2) : 172 - 179
  • [6] Group 4 transition metal CH2=MF2, CHF=MF2, and HC/MF3 complexes formed by C-F activation and α-fluorine transfer
    Lyon, Jonathan T.
    Andrews, Lester
    INORGANIC CHEMISTRY, 2007, 46 (12) : 4799 - 4808
  • [7] (Fluoromethylsulfonyl)methylation of Quinoxalinones Using NaSO2CH2F for C-F Bond Cleavage
    Dai, Peng
    Li, Yufei
    Chen, Yu
    Jiao, Jian
    Wang, Qingqing
    Li, Chenxiao
    Gu, Yucheng
    Zhang, Yanbin
    Xia, Qing
    Zhang, Wei-Hua
    ORGANIC LETTERS, 2022, 24 (06) : 1357 - 1361
  • [8] Formation and characterization of the uranium methylidene complexes CH2=UHX (X = F, C, and Br)
    Lyon, JT
    Andrews, L
    INORGANIC CHEMISTRY, 2006, 45 (04) : 1847 - 1852
  • [9] Calculations of the interaction energies of CH2=CH2, CH=CH, C=O with Cl-F by ab-initio methods
    Esteyez, J
    Rodriguez, V
    Arias, B
    Estevez, J
    Hernandez, S
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1996, 211 : 429 - CHED
  • [10] Calculations of the interaction energies of CH2=CH2, CH=CH, C=O with Cl-F by semi-empirical methods
    Esteyez, J
    Rodriguez, V
    Arias, B
    Rivera, L
    Estevez, L
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1996, 211 : 428 - CHED
12345